H. Fischer (auth.), H. Fischer (eds.)'s Alkoxyl, Carbonyloxyl, Phenoxyl, and Related Radicals PDF

By H. Fischer (auth.), H. Fischer (eds.)

ISBN-10: 3540473777

ISBN-13: 9783540473770

ISBN-10: 3540560572

ISBN-13: 9783540560579

Free radicals, that are key intermediates in lots of thermal, photochemical and radiation strategies, are vital for a formal knowing of primary usual approaches and the profitable improvement of natural syntheses. Volume II/18 serves as a complement and extension to volume II/13 and covers expense constants and different kinetic facts of loose radical reactions in beverages. Furthermore II/18 comprises new chapters on reactions of radicals in excited states and of carbenes, nitrenes and analogues. chosen species in aqueous recommendations for which different compilations can be found have been intentionally passed over as earlier than, and for a similar cause electron move equilibria of natural radicals weren't covered.

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Additional resources for Alkoxyl, Carbonyloxyl, Phenoxyl, and Related Radicals

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73 Landolt-Börnstein New Series II/18D1 Ref. p. / add. ref. Rate data [C4H9O] a (CH3)3 CO CH3 COCH3 + CH2CH3 (CH3)3 CO b + Therm. 66 M–1 88 ) 85Lis1 [C4H9O] a (CH3)3 CO (CH3)3 CO CH3 COCH3 N + CH + CH3 b X Therm. 1 · 106 M–1 s –1 at 393 K, see footnote 73). 72 (corr. coeff. 81 (corr. coeff. 977). 90 ) Corrected for hydrogen atom abstraction from methyl group. 1 Alkoxyl radicals Radical’s gross formula Reaction Radical generation Method Solvent T [K] [Ref. p. / add. ref. Rate data [C4H9O] a (CH3)3 CO (CH3)3 CO CH3 COCH3 CH + + CH3 b N (CH3)3 COH + X Therm.

8 · 108 M–1 s –1 95Val1 [C4H9O] (CH3)3 CO CH3 HO + CH2(CH2CH2CHCH2)3H S CH3 O (CH3)3 COH + Laser phot. 1 nm, up 10 mJ, ≈ 8 ns) of DTBP RT 1) KAS C6H6 /DTBP (3 : 1, V/V) 1 ) Assumed, not provided in the reference. 1 Alkoxyl radicals Radical’s gross formula Reaction Radical generation Method Solvent T [K] [Ref. p. / add. ref. Rate data [C4H9O] (CH3)3 CO CH3 DO + CH2(CH2CH2CHCH2)3H O CH3 O (CH3)3 COD + CH2(CH2CH2CHCH2)3H O Laser phot. 45 · 108 M–1 s –1 [C4H9O] (CH3)3 CO + O CH3 39) CH3 product(s) 2 O-gentiobiose Pulse rad.

Of [(CH3)3COOC(O)]2 PR, NRT substrate/acetone 333 [C4H9O] 44 • a –– (CH3)3CO • –––– ➝ CH3COCH3 + CH3 • – (CH3)3COCH2CF2 b–––➝ – (CH3)3CO • + CH2 –– CF2 ––– c –––➝ – • (CH3)3COCF2CH2 Therm. 35 44) 44 ) 85Cut1 ) Calculated by the reviewer from the product ratio and substrate concentrations given in the reference. 1 Alkoxyl radicals Solvent T [K] [C4H9O] [Ref. p. / add. ref. Rate data • a –– ➝ CH3COCH3 + CH3 (CH3)3CO • –––– • b –– ➝ (CH3)3COCH2CH2 (CH3)3CO • + CH2 –– CH2 –––– Therm. 15 M–1 333 44 ) 85Cut1 • a –– (CH3)3CO • –––– ➝ CH3COCH3 + CH3 • b –– ➝ (CH3)3COH + CH3SCH2 (CH3)3CO • + (CH3)2S –––– Therm.

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Alkoxyl, Carbonyloxyl, Phenoxyl, and Related Radicals by H. Fischer (auth.), H. Fischer (eds.)


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